Origin Of OZONE
The photochemical mechanisms that give rise to
the ozone layer were discovered by the British physicist Sidney Chapman in
1930. Ozone in the Earth's stratosphere is created by ultraviolet light
striking oxygen molecules containing two oxygen atoms (O2),
splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen
then combines with unbroken O2 to create ozone, O3. The
ozone molecule is also unstable (although, in the stratosphere, long-lived) and
when ultraviolet light hits ozone it splits into a molecule of O2
and an atom of atomic oxygen, a continuing process called the ozone-oxygen
cycle, thus creating an ozone layer in the stratosphere, the region from about
10 to 50 kilometers (33,000 to 160,000 ft) above Earth's surface. About 90% of
the ozone in our atmosphere is contained in the stratosphere. Ozone
concentrations are greatest between about 20 and 40 kilometers (12 and 25 mi),
where they range from about 2 to 8 parts per million. If all of the ozone were
compressed to the pressure of the air at sea level, it would be only 3
millimeters thick.
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